HAPPY Dyes as Light Amplification Media in Thin Films
نویسندگان
چکیده
A series of 1H amorphous tri-phenyl pyridine (HAPPY) dyes have been synthesized from luminescent triphenyl-group-containing 2-methyl-6-styryl-substituted-4H-pyran-4-ylidene derivatives in reactions with benzylamine and investigated for suitability as solution-processable light-emitting medium components thin films amplified spontaneous emission (ASE). Conversion a 4H-pyrane ring into 1H-pyridine fragment enables aggregation-induced enhancement (AIEE) behavior the target products slightly increases thermal stability, glass transition temperatures, ASE efficiency PLQY up to 15% thresholds low 46 μJ/cm2 neat spin-cast films, although photophysical properties are mostly dominated by incorporated electron acceptors. Continued lasing parameter improvement experiments revealed that no further optimization HAPPY doping polymer matrixes is required were lowest pure due AIEE phenomenon.
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ژورنال
عنوان ژورنال: Journal of Organic Chemistry
سال: 2021
ISSN: ['1520-6904', '0022-3263']
DOI: https://doi.org/10.1021/acs.joc.0c02574